PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 Locks Studs(TM) High Strength Threadlocker 81791 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Locks Studs(TM) High Strength Threadlocker Item No.: 81791 Product Type: Anaerobic 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Polyglycol dimethacrylate 25852-47-5 65-70 Bisphenol A fumarate resin 39382-25-7 20-25 CUMENE HYDROPEROXIDE* 80-15-9 1-3 Poly(ethylene) 9002-88-4 1-3 SACCHARIN 81-07-2 1-3 N,N-Dialkyltoluidines 613-48-9 0.1-1 SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 112945-52-5 0.1-1 * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA resp. dust Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) 3. HAZARDS IDENTIFICATION Toxicity: Mild eye irritant. Oral LD50 more than 10,000 mg/kg. Dermal LD50 more than 5000 mg/kg. Primary Routes of Entry: Eyes, skin Signs and symptoms of Exposure: May cause dermatitis on prolonged contact in sensitive individuals Existing Conditions Aggravated by Exposure: None known PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Product Name: Locks Studs(TM) High Strength Threadlocker Item No.: 81791 3. HAZARDS IDENTIFICATION (continued) Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Polyglycol dimethacrylate ALG IRR NO NO NO Bisphenol A fumarate resin ALG IRR NO NO NO CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO Poly(ethylene) No Data NO N/A NO SACCHARIN No Data YES 2B NO N,N-Dialkyltoluidines No Data NO NO NO SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE NUI NO N/A NO ------------------------------------------------------------------------------- Abbreviations N/A Not Applicable 2B Possibly carcinogenic to humans ALG Allergen CNS Central nervous system COR Corrosive IRR Irritant MUT Mutagen NUI Nuisance dust 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention Inhalation: Does not apply Skin Contact: Wash thoroughly with soap and water Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200°F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Irritating organic vapors Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower Not available (% by volume in air)Upper Not available PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 05 Product Name: Locks Studs(TM) High Strength Threadlocker Item No.: 81791 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Soak up in an inert absorbent. Store in a partly filled, closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Store below 100°F (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid prolonged skin contact. Keep away from eyes. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Neoprene, rubber, or butyl rubber gloves. Ventilation: Does not apply See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Red liquid Odor: Mild Boiling Point: More than 300°F pH: Does not apply Solubility in Water: Slight Specific Gravity 1.05 at 80°F Volatile Organic Compound (EPA Method 24) 13.5%; 141.75 g/l Vapor Pressure: Less than 5mm at 80°F Vapor Density: Not available Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: None Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION See Section 3. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 05 Product Name: Locks Studs(TM) High Strength Threadlocker Item No.: 81791 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None 15. REGULATORY INFORMATION CA Proposition 65: This product contains Saccharin. No prop65 hazard warning is necessary if this product is used as reasonably anticipated. 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 1 Fire Hazard: 1 Reactivity Hazard: 1 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 1 Flammability Hazard: 1 Reactivity Hazards: 1 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Environmental Health & Safety PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 05 Product Name: Locks Studs(TM) High Strength Threadlocker Item No.: 81791 16. OTHER INFORMATION (continued) Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: January 22, 1996 Revision: 0028